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It's only the unbound portion of testosterone that is able to actually exert the biological influence. So, we pay very special attention to how much testosterone is 'free'—and free is defined as the testosterone that is neither bound to SHBG or
albumin.
Peter Attia
Free Testosterone Isn't Bound to Albumin or Sex Hormone-Binding Globulin
AMA #28: All things testosterone and testosterone replacement therapy
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